Room-temperature ferromagnetism in (K0.5Na0.5)NbO3-xBaNi(0.5)Nb(0.5)O(3-delta) ferroelectric ceramics with narrow bandgap
CERAMICS INTERNATIONAL(2021)
摘要
In this paper, a simple, reproducible and cost-effective solid-state reaction sintering process is developed to fabricate (K0.5Na0.5)NbO3-xBaNi(0.5)Nb(0.5)O(3-delta) (KNN-xBNN) ceramics with a narrow bandgap and room-temperature ferromagnetism. Here, we report a systematic investigation of the influence of the BaNi0.5Nb0.5O3-delta (BNN) concentration on the properties of KNN-xBNN ceramics. All ceramics form orthorhombic perovskite structures with a space group Amm2 and a weak peak at the wavelength of 550 cm(-1) that is characteristic of the pillow shoulder of the orthorhombic phase. KNN-xBNN ceramics with x between 0.02 and 0.08 have a narrow bandgap of about 2.5 eV-much smaller than the 3.5 eV of its parent (K0.5Na0.5)NbO3 (KNN) ceramic-which is attributed to Ni2+-oxygen vacancy combinations (Ni2+-V-O) raising the valence electron energy level of the KNN ceramic. Furthermore, doping BNN into KNN ceramics can significantly convert the magnetism from diamagnetism to ferromagnetism and the component of x = 0.08 achieves both maximum saturation magnetisation intensity (14 memu/g) and minimum coercive magnetic field (80 Oe). Our findings provide a systematic insight into the bandgap tunability and ferromagnetism induction at room temperature in lead-free perovskite KNN-xBNN ceramics, as well as demonstrate their potential applications in perovskite solar cells and multiferroic devices.
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关键词
K0.5Na0.5)NbO3-xBaNi(0.5)Nb(0.5)O(3-delta) ceramics,Narrow bandgap,Ferroelectricity,Ferromagnetism
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