The Synthesis of 1,4-Dihydroquinoline-3-carboxylates from 2-Benzoyl-3-[2-(dialkylamino)aryl]acrylates

Dmitrii S. Ivanov,Alexander Yu. Smirnov, Mikhail S. Baranov

Chemistry of Heterocyclic Compounds（2024）

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摘要

A method for the synthesis of 1,4-dihydroquinoline-3-carbonyl compounds from 2-benzoyl-3-[2-(dialkylamino)aryl]acrylates via the sequence of 1,5-hydride shift, dealkylation, and cyclization processes was proposed. The reaction products contained a push-pull enamine fragment.

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关键词

dihydroquinoline,carboxylates,push,pull enamines,dealkylation,hydride shift

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