Tailoring the Surface Topography and Crystallinity of EuMnO3 Films: A Study on Sintering Effects

We obtained EuMnO3 films through a sol-gel process at varying temperatures, aiming to investigate spatial layout variations influenced by different sintering temperatures. Our results indicate that films adopt an orthorhombic structure when sintered between 800°C and 850°C, accompanied by a reduction in nanocrystal size during annealing. Surface analysis reveals that films processed at higher temperatures exhibit increased roughness, negative asymmetry, heightened kurtosis, elevated peak densities, and more distinct peak forms. Furthermore, these films display surfaces with greater anisotropy and lower spatial frequencies compared to those sintered at lower temperatures. Nevertheless, fractal analysis uncovers that both the EuMnO800 and EuMnO850 samples showcase heightened spatial complexity, a more uniform nanotexture, optimal surface porosity, and improved topographic consistency. The findings suggest that films sintered at 800°C display a spatial arrangement with superior topographic qualities, rendering them potentially valuable for the advancement of semiconductor films derived from perovskite rare-earth oxides for various technological applications.