A review on the advancement in photocatalytic degradation of poly/perfluoroalkyl substances in water: Insights into the mechanisms and structure-function relationship

Poly/perfluoroalkyl substances (PFAS) are persistent organic pollutants and ubiquitous in aquatic environment, which are hazardous to organisms and human health. Several countries and regions have taken actions to regulate or limit the production and emission of some PFAS. Even though a series of water treatment technologies have been developed for removal of PFAS to eliminate their potential adverse effects, the removal and degradation performance are usually unsatisfactory. Photocatalytic degradation of PFAS is considered as one of the most effective approaches due to the mild operation conditions and environmental friendliness. This review systematically summarized the recent advances in photocatalytic degradation of PFAS based on heterogeneous photocatalysts, including TiO2-, Ga2O3-, In2O3-, ZnO-, Bi-based, and others. Overall, two mainly degradation mechanisms were involved, including photo-oxidation (involving the holes and oxidative radicals) and photo-reduction types (by e− and reductive radicals). The band structures of the photocatalysts, degradation pathways, structure-function relationship, and impacting factors were further discussed to elucidate the essential reasons for the enhanced degradation of PFAS. Furthermore, the review identified the major knowledge gaps to solve the issues of photocatalysis in real application. This paper also propounded several strategies to promote the design and optimization of high-efficient photocatalysts, and meet the challenges to remove PFAS through photodegradation technologies.