Structure and IR Spectroscopic Study of Sodium Tris(monoiodacetato)uranilate
Radiochemistry(2024)
Abstract
NaUO2(mia)3 (I) crystals (mia: monoiodacetate ion CH2ICOO−) were synthesized and studied by X-ray diffraction and IR spectroscopic analyses. Uranyl-containing complexes [UO2(mia)3]– in the structure correspond to the crystal chemical formula A(B01)3, where A = UO22+, B01 = mia. Using coordination sequences, we analyzed the features of the 3D framework, which is realized in the structure of crystals of I and contains 8 crystallographically nonequivalent U or Na atoms. A semiempirical calculation and comparison of the calculated and experimental vibration frequencies in the IR spectrum of I were performed.
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Key words
uranyl,iodacetates,complexes,crystal structure,Voronoi–Dirichlet polyhedra,IR spectra
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