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Selective area epitaxy of in-plane HgTe nanostrcutures on CdTe(001) substrate

arxiv(2024)

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摘要
Semiconductor nanowires are believed to play a crucial role for future applications in electronics, spintronics and quantum technologies. A potential candidate is HgTe but its sensitivity to nanofabrication processes restrain its development. A way to circumvent this obstacle is the selective area growth technique. Here, in-plane HgTe nanostructures are grown thanks to selective area molecular beam epitaxy on a semi-insulating CdTe substrate covered with a patterned SiO_2 mask. The shape of these nanostructures is defined by the in-plane orientation of the mask aperture along the <110>, <11̅0>, or <100> direction, the deposited thickness, and the growth temperature. Several micron long in-plane nanowires can be achieved as well as more complex nanostructures such as networks, diamond structures or rings. A good selectivity is achieved with very little parasitic growth on the mask even for a growth temperature as low as 140C and growth rate up to 0.5 ML/s. For <110> oriented nanowires, the center of the nanostructure exhibits a trapezoidal shape with 111B facets and two grains on the sides, while <11̅0> oriented nanowires show 111A facets with adatoms accumulation on the sides of the top surface. Transmission electron microscopy observations reveal a continuous epitaxial relation between the CdTe substrate and the HgTe nanowire. Measurements of the resistance with fourpoint scanning tunneling microscopy indicates a good electrical homogeneity along the main NW axis and a thermally activated transport. This growth method paves the way toward the fabrication of complex HgTe-based nanostructures for electronic transport measurements.
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