Elemental Distribution in Catalyst-Coated Membranes of Proton Exchange Membrane Water Electrolysers Tracked by Synchrotron X-Ray Fluorescence
ADVANCED ENERGY AND SUSTAINABILITY RESEARCH(2024)
Abstract
The stability of catalyst layers and membranes in proton exchange membrane water electrolysis (PEMWE) cells represents an ongoing challenge, compounded by the dissolution of components and migration of elements within the catalyst-coated membrane (CCM). Conventional microscopy methods often struggle to efficiently evaluate large cross-sections of PEMWE membranes, which is essential for representative analysis of technical scale CCMs. Herein, synchrotron radiation-based X-Ray fluorescence microscopy is exploited to analyze the stability of CCMs with around 1 mu m resolution and a field of view of approximate to 200 x 75 mu m2. Three application scenarios are investigated: 1) migration of catalyst elements, 2) dissolution of components, and 3) contaminated water supply containing Fe2+$\left(\text{Fe}\right)<^>{2 &amp;amp;plus;}$ ions. XRF is performed at three different X-Ray energies (11.7, 11.4, and 11.0 keV), revealing the local elemental composition, including Pt, Ir, Ti, and Fe, under different stressing conditions. Notable observations include the distribution of Ir across the membrane and in the cathode catalyst layer, localization of Pt within the membrane, accumulation of Ti in the cathode catalyst layer, and minimal presence of Fe. XRF has been demonstrated to be a powerful analytical tool for accurate and high throughput imaging of catalyst degradation in PEMWE scenarios, particularly of technical scale devices. Synchrotron radiation-based X-Ray fluorescence tracks material stability in proton exchange membrane water electrolysis cells. Dissolution and migration of Pt, Ir, and other elemental components between the catalyst layers and membrane are visualized with high sensitivity in terms of operating conditions, offering a powerful tool to study the degradation of technical scale devices.image (c) 2024 WILEY-VCH GmbH
MoreTranslated text
Key words
catalyst-coated membranes,material stability,metal migration,proton exchange membrane water electrolysis,X-Ray fluorescence
AI Read Science
Must-Reading Tree
Example
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
Generate MRT to find the research sequence of this paper
Chat Paper
Summary is being generated by the instructions you defined