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Contact-Engineering of Self-Aligned-Gate Metal Oxide Transistors Processed via Electrode Self-Delamination and Rapid Photonic Curing

ADVANCED FUNCTIONAL MATERIALS(2024)

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Abstract
Metal oxide thin-film transistors (TFTs) offer remarkable opportunities for applications in emerging transparent and flexible microelectronics. Unfortunately, their performance is hindered by limitations associated with parasitic effects, such as parasitic electrode overlap capacitances and high contact resistance, which can severely limit their dynamic behavior. Here, an innovative method is reported to fabricate coplanar self-aligned-gate (SAG) indium-gallium-zinc-oxide (IGZO) transistors with engineered source/drain contacts. The manufacturing process starts with the deposition and patterning of a gate electrode/dielectric stack and its functionalization with an organic self-assembled monolayer (SAM) as the surface energy modifier. A second gold (Au) electrode is subsequently deposited over the gate electrode stack. The overlapping region between the two electrodes is removed via self-delamination under mild sonication, forming perfectly aligned coplanar Au-Gate-Au electrodes. Device fabrication is completed with the spin coating of the IGZO precursor, followed by rapid photonic curing. Replacing the gold source/drain contact with bimetallic electrodes such as Au/In and Au/ITO enables a reduction in contact resistance and improves the transistor performance remarkably without increasing manufacturing complexity. The method is highly scalable, robust, and applicable to other semiconductor materials. Self-aligned gate transistors are developed with bilayer source/drain electrodes and a photonically cured indium-gallium-zinc-oxide as the semiconducting channel. The proposed transistor architecture minimizes the overlap capacitances and access resistance while enabling precise electrode work function engineering without increasing manufacturing complexity. The ensuing transistors exhibit high electron mobility, small subthreshold swing, and low contact resistance. image
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Key words
contact resistance,indium-gallium-zinc-oxide,metal oxide semiconductors,photonic curing,self-aligned gate transistors,thin-film transistors
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