Investigation on the activity of Ni doped Ce 0.8 Zr 0.2 O 2 for solar thermochemical water splitting combined with partial oxidation of methane

The incredible potential of metal oxide -based two-step solar -driven thermochemical water splitting technology lies in its ability to harness limitless solar energy to produce clean and renewable hydrogen fuel. However, achieving high redox kinetics and lowering the reaction temperature remain the primary challenges in hydrogen production. The CeO 2 - ZrO 2 system is a well-known oxygen carrier for thermochemical water splitting on account of its high temperature stability, quick kinetics, and redox cyclability. While recent studies have explored the combination of methane partial oxidation with metal oxide reduction, the reduction effect of cerium -zirconium oxide is relatively low, and reactivity still needs improvement. The nickel -doped system exhibits good redox performance and is regenerative. In this study, different mass percentages nickel -loaded oxygen carriers mNi/ Ce 0.8 Zr 0.2 O 2 (m = 0, 1, 3, 5, 7, 9) were prepared using the impregnation method. Redox properties of oxygen carriers were investigated in a fixed bed reactor and various characterizations were performed. To assess the durability of mNi/Ce 0.8 Zr 0.2 O 2 , 60 long -cycle experiments were also conducted. The results indicate that the lattice oxygen in mNi/Ce 0.8 Zr 0.2 O 2 exhibits remarkable selectivity for the partial oxidation of CH 4 at temperatures ranging from 880 to 925 degrees C. The best reactivity performance was achieved with a nickel loading ratio of 5 wt%, and after 60 consecutive redox cycles, 5Ni/Ce 0.8 Zr 0.2 O 2 demonstrates remarkable robustness, maintaining its redox activity.