Disparate reactivity of a chiral iron(II) tetracarbene complex with organic azides
DALTON TRANSACTIONS(2024)
Abstract
A chiral tetra-NHC iron(II) complex and its disparate reactivity with multiple organic azides is reported. Both aryl and alkyl azides react with the iron(ii) complex yielding three distinct products: an iron(iv) imide, an iron(IV) tetrazene, and a surprising and unprecedented double imide insertion complex.
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