Effect of CO2-H2O Interaction with High-Rank Coal on Mechanical Properties and Acoustic Emission Characteristics under Confining Pressure.

The adsorption of CO2 by coal leads to changes in its mechanical properties, particularly when considering supercritical CO2 and water with supercritical CO2 adsorption. This is strongly linked to the efficiency of CO2-enhanced coalbed methane (CO2-ECBM) extraction and the safety of CO2 geological storage. This study focuses on 3# coal from the Datong Mine in Gaoping City, Shanxi Province. The high-rank coal's mechanical properties, including the triaxial compressive strength and elastic modulus, were examined under the combined effects of CO2 injection pressure, CO2 injection time, and moisture content. The triaxial compressive strength and elastic modulus of the coal showed a decrease following CO2 injection. Increasing the CO2 injection pressure, prolonging the CO2 injection time, and increasing the moisture content were favorable for coal softening. In particular, the triaxial compressive strength and elastic modulus of the coal sample after 144 h of water and supercritical CO2 softening decreased by 67.67 and 64.15%, respectively. Injecting CO2 into coal changed its failure mode. The dry raw coal sample exhibited a brittle shear failure mode, while the coal samples showed transitional shear failure after injecting 6 MPa CO2 and 8 MPa CO2 and ductile nondilatant barreling failure after injecting water and 8 MPa CO2 (with a moisture content of 3.02%). Moreover, the cumulative acoustic emission energy of the coal samples followed a similar trend to the decrease in mechanical properties under different conditions. The physical and chemical interactions among coal, CO2, and water caused the softening of coal; these included the generation of the swelling stress, the dissolution of minerals by carbonate solutions, the reduction in surface energy of coal owing to CO2 adsorption, and the extraction and plasticization reactions of organic matter in coal. The research results are of great significance for further understanding CO2-ECBM and CO2 geological sequestration.