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Significance of the connecting position between Zn(ii) porphyrin and Re(i) bipyridine tricarbonyl complex units in dyads for room-temperature phosphorescence and photocatalytic CO2reduction: unexpected enhancement by triethanolamine in catalytic activity

Yusuke Kuramochi,Yuto Suzuki, Somyo Asai,Tomohiro Suzuki, Hiroki Iwama,Motoko S. Asano,Akiharu Satake

Chemical Science（2023）

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Abstract
In three Zn porphyrin–Re complex dyads, we explored room-temperature phosphorescence and photocatalytic CO2reduction. The dyad with a 5-position linkage to the bipyridine ligand showed notable activity due to dual triethanolamine coordination to Zn and Re ions.
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