Oxidative hydrolysis of aliphatic bromoalkenes: scope study and reactivity insights.

Beilstein journal of organic chemistry(2024)

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摘要
We have developed an operationally simple method for the synthesis of dialkyl α-bromoketones from bromoalkenes by utilizing a hypervalent iodine-catalyzed oxidative hydrolysis reaction. This catalytic process provides both symmetrical and unsymmetrical dialkyl bromoketones with moderate yields across a broad range of bromoalkene substrates. Our studies also reveal the formation of Ritter-type side products by an alternative reaction pathway.
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关键词
bromoalkenes,bromoketones,hypervalent iodine,oxidative hydrolysis,ritter-type
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