A new high-pressure die casting Mg−Gd−Sm−Al alloy with high strength-ductility synergy

A high-pressure die casting (HPDC) Mg−5Gd−1.5Sm−0.7Al alloy was newly developed and exhibits outstanding strength-ductility synergy, with the yield strength and the tensile elongation to fracture being approximately 200 MPa and 8.5%, respectively. This alloy has two types of α-Mg grains: coarse α1-Mg ((46 ± 18) μm) and fine α2-Mg ((9.2 ± 2.3) μm) grains, and various Al-GS (GS = Gd and Sm) particles located at grain boundaries while clear solute-atom segregation near grain boundaries with limited or free intermetallic particles. Characterizations using Cs-corrected high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) indicate the crystal structures of Al-GS phases. After aging, dense β’ precipitates and chain-shaped β’’-like structures precipitated near grain boundaries while a high density of ultrafine β’’-(Mg,Al)3Sm precipitates and Al-GS clusters formed in grain center. Relatively fine grains, Al-GS primary particles, solute-atom segregation near grain boundaries, and/or multiple precipitates contribute to the high strength of the studied alloy, while the multi-scale α-Mg grains, variety of intermetallic particles but discontinuous skeleton, and the multi-typed precipitated lead to its satisfactory ductility.