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Photoredox/copper-catalyzed gem-difluoroalkylation-cyanation of 1,3-enynes.

Yachen Wang,Shuai Liu,Yangen Huang

Organic & biomolecular chemistry（2024）

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Abstract
A photoredox/copper-catalyzed 1,4-difunctionalization of 1,3-enynes with readily available difluoroalkylating reagents and TMSCN was developed. This reaction proceeded at mild conditions, affording the corresponding difluoroalkylated allenes in good yields with high functional-group tolerance and excellent regioselectivity.
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