Dielectric spectroscopic study of the binary mixtures of N-Hexanol with N,N-Dimethylformamide in the frequency range of 20 Hz to 2 MHz

N. A. Chaudhary,K. N. Shah, C. R. Vaja, V. A. Rana, A. N. Prajapati

International Journal of Modern Physics B(2024)

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摘要
A precision LCR meter with a liquid dielectric cell was used for complex dielectric function [Formula: see text] of binary mixtures of N-Hexanol (n-HxOH) and N,N-Dimethylformamide (DMF) in the frequency range of 20[Formula: see text]Hz to 2[Formula: see text]MHz at 293.15[Formula: see text]K temperature. The data were utilized for various formalisms such as complex modulus spectra ([Formula: see text]), complex impedance spectra ([Formula: see text]), and complex conductivity spectra ([Formula: see text]). Complex permittivity data were fitted to the Cole–Cole Model. Different relaxation times like electrode polarization ([Formula: see text]), relaxation time ([Formula: see text]), and ionic conduction relaxation time ([Formula: see text]) were calculated and reported. Parameters like Debye Length ([Formula: see text]), Ion Mobility ([Formula: see text]), Mobile Ion Concentration ([Formula: see text]), and Ion Diffusivity (D) were determined. The study is used to determine the effect of concentration dependent on different dielectric and electrical properties of the binary mixtures.
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