Evolution of collisional condensation of biodiesel combustion particulate matter in engine exhaust pipe

To investigate the evolution of biodiesel combustion particulate matter (PM) within the engine exhaust system, PM samples were analyzed from diesel fuel, soybean oil methyl ester (SME), catering waste oil methyl ester (WME) and palm oil methyl ester (PME) at various locations along the engine exhaust pipe, and a gas-solid two-phase flow model of exhaust gas and PM was developed using the coupled computational fluid dynamics-discrete element method (CFD-DEM). The results indicate that the average primary particle diameter of biodiesel PM is smaller than that of diesel PM at the same position within the exhaust pipe, and it exhibits an increasing trend with respect to the iodine value of biodiesel. The adhesion forces of diesel, SME, WME, and PME PM at 0m downstream from the exhaust pipe were measured as 9.83 nN, 16.74 nN, 26.54 nN, and 34.31 nN, respectively. The biodiesel PM with higher mass density readily formed structurally stable particulate agglomerates at the inlet of the exhaust pipe. With an increase in exhaust flow velocity, there was a corresponding rise in particle collision frequency. The initial agglomeration probability of particles exhibited an increase followed by a subsequent decrease. The normal overlap of particle collisions decreased with an increase in the Young’s modulus of the particles, thereby reducing the likelihood of adsorption and adhesion during particle collision and hindering the formation of a greater number of particle aggregates.