Introducing AFS ([Al(SO3F)3]x) – a thermally stable, readily available, and catalytically active solid Lewis superacid

Common Lewis superacids often suffer from low thermal stability or complicated synthetic protocols, requiring multi-step procedures and expensive starting materials. This prevents their large-scale application. Herein, the easy and comparably cheap synthesis of high-purity aluminium tris(fluorosulfate) ([Al(SO3F)3]x, AFS) is presented. All starting materials are commercially available and no work-up is required. The superacidity of this thermally stable, polymeric Lewis acid is demonstrated using both theoretical and experimental methods. Furthermore, its synthetic and catalytic applicability, e.g. in bond heterolysis reactions and C–F bond activations, is shown.