An alternative total synthesis of Aigialomycin D

Sudhakar D G S, Venkata Ramana Reddy Ch,Tasqeeruddin Syed,Gattu Sridhar,Srinivasa Rao Alapati

Synthetic Communications（2024）

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摘要

Aigialomycin D, a 14-membered benzannulated macrolactone, was synthesized in a simple, efficient and stereoselective approach using inexpensive and commonly accessible starting materials. The main steps in this convergent synthesis are Corey-Fuchs reaction, Yamaguchi esterification and ring closing metathesis (RCM).

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关键词

Resorcylic acid lactones,aigialomycins,Corey-Fuchs reaction,Wittig olefination,Yamaguchi macrolactonization

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