High-Performance Cobalt Chalcogenides for Oxygen Reduction Reaction

The oxygen reduction reaction (ORR) is vital to numerous energy conversion technologies, such as fuel cells and metal-air batteries. Moreover, to enhance the overall efficacy and durability of these devices, it is crucial to develop catalysts that are both effective and economical. Among the many explored catalyst materials, cobalt chalcogenides have attracted considerable interest due to their unique properties and exceptional ORR performance. This review focuses on the synthesis methods, structural characteristics, and electrochemical performance of high-performance cobalt chalcogenides as catalysts for the ORR. In addition, the influence of various synthetic parameters on the catalytic activity and stability of cobalt chalcogenides is investigated. Also addressed are the effects of defects, doping, and surface modification on the ORR performance of cobalt chalcogenides. In addition, the use of cobalt chalcogenides in practical fuel cell devices is discussed, along with their outstanding performance as ORR catalysts in both acidic and alkaline environments. The durability and long-term stability of cobalt chalcogenides under severe operating conditions are evaluated, indicating their potential commercial applications. Finally, the field of cobalt chalcogenides for ORR challenges and prospects are outlined. This review proposes strategies for further enhancing their catalytic activity, selectivity, and durability, such as interface engineering and synergistic combinations with other catalyst materials. For researchers working on the development of next-generation ORR catalysts and the practical implementation of cobalt chalcogenides for sustainable energy applications, the insights garnered from this review are invaluable.