Heavy metals in urban soil: Contamination levels, spatial distribution and human health risk assessment (the case of Ufa city, Russia)

The article examines the concentration of 9 heavy metals (Hg, Pb, Zn, Cr, Co, Ni, Cu, Ba and V) and As in the soil cover of the urban area in one of the largest cities in Russia, Ufa (the Republic of Bashkortostan). It is compared with aggregated data of concentrations on urbanized areas in surface soils throughout the world. For elements exceeding the average background values in soils of the urban area (Cr, Ni, Cu and Co), the average concentrations in the city soils were 346, 101, 51 and 18 ppm, respectively. Using enrichment factor (EF), geoaccumulation index (Igeo), and concentration coefficients (CC), Cr and Ni were identified as elements entering the soil cover as a result of anthropogenic pollution. Although the level of their enrichment and contamination of soils in the most territory of the city corresponds to the moderate class, there are sites with critical threshold values. Spatial analysis of heavy metals distribution was carried out based on the results of pollution load index (PLI) and ecological risk factor (Er) calculations with the use of graphical presentation of results, which allowed specific and detailed description of sites calling for special attention. The use of cluster analysis allowed dividing the sample of chemical elements into groups with probably similar sources of entry into the environment. Monte Carlo modeling of risk calculation showed negligible non-cancer risks for both adult and child populations in most of the city. While children's exposure to Cr was of concern in the more residential part of the city, free of large industrial plants, As posed a threat with respect to cancer risks in the southern part of the city, with elevated concentrations and other HMs in vicinity of the oil refineries.