Visible‐Light‐Mediated Catalyst and Additive‐Free C(sp3)−H Phosphorylation of Glycine Ester Derivatives

We herein report a visible light induced dehydrogenative phosphonylation reaction of glycine derivatives and di‐aryl phosphine oxides. A diverse range of phosphine‐glycine derivatives were constructed under ambient condition in the absence of catalyst and additives. A plausible mechanism was also proposed.