Improved biological methanation using tubular foam-bed reactor

Biotechnology for Biofuels and Bioproducts(2024)

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摘要
Power-to-gas is the pivotal link between electricity and gas infrastructure, enabling the broader integration of renewable energy. Yet, enhancements are necessary for its full potential. In the biomethanation process, transferring H2 into the liquid phase is a rate-limiting step. To address this, we developed a novel tubular foam-bed reactor (TFBR) and investigated its performance at laboratory scale. A non-ionic polymeric surfactant (Pluronic® F-68) at 1.5 (L_CH_4/L_R/d) , with a CH4 concentration exceeding 90 L_CH_4/L_R/d while maintaining the grid quality CH4. Despite, reduced gas–liquid solubility and gas–liquid mass transfer at higher temperatures, the twofold increase in MPR compared to phase (II) might be attributed to other factors, i.e., higher metabolic activity of the methanogenic archaea. To assess process robustness for phase (II) conditions, a partial H2 feeding regime (12 h 100 L_CH_4/L_R/d even with intermittent, low H2 concentration. Overall, the TFBR’s performance plant sets the course for an accelerated introduction of biomethanation technology for the storage of volatile renewable energy. Robust process performance, even under H2 starvation, underscores its reliability. Further steps towards an optimum operation regime and scale-up should be initiated. Additionally, the use of TFBR systems should be considered for biotechnological processes in which gas–liquid mass transfer is a limiting factor for achieving higher reaction rates.
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关键词
Biomethane,Biological methanation,Hydrogen starvation,Polymeric non-ionic surfactant,Power storage,Power to gas,Tubular foam-bed reactor,Variable renewable energy
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