Recent advances in dynamic reconstruction of electrocatalysts for carbon dioxide reduction

Electrocatalysts undergo structural evolution under operating electrochemical CO2 reduction reaction (CO2RR) conditions. This dynamic reconstruction correlates with variations in CO2RR activity, selectivity, and stability, posing challenges in catalyst design for electrochemical CO2RR. Despite increased research on the reconstruction behavior of CO2RR electrocatalysts, a comprehensive understanding of their dynamic structural evolution under reaction conditions is lacking. This review summarizes recent developments in the dynamic reconstruction of catalysts during the CO2RR process, covering fundamental principles, modulation strategies, and in situ/operando characterizations. It aims to enhance understanding of electrocatalyst dynamic reconstruction, offering guidelines for the rational design of CO2RR electrocatalysts.