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Crystal epitaxy-confined Pd, Ti-bimetallic sites in the MFI zeolite for benzylalcohol oxidation.

Wenchao Xu, Jianyuan Su, Xiang Ni,Qifan Yang, Wenwen Song,Lei Wang,Hongjun Zhu

Chemical communications (Cambridge, England)（2024）

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Abstract
A general strategy for confining Pd, Ti-bimetallic sites in the MFI zeolite by crystal epitaxy was developed. The tailored spatial intimacy of the bimetallic sites demonstrated distinct catalytic performance for the oxidation of benzylalcohol. The related mechanism was clarified and afforded a valuable pathway for rational catalyst design.
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