Influence and regulation of hydrogen content in pure copper rod billet during negative pressure continuous casting process

Journal of Materials Science(2024)

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摘要
The regulation of hydrogen content in the continuous casting process is conducive to the reduction of pore defects in the casting billet. In this paper, the influence of negative pressure (NP) and continuous casting speed (CCS) on hydrogen content in copper rod billet prepared by negative pressure continuous casting (NPCC) technique was analyzed, and the mechanism of the coordinated coupling of NP and melt flow on hydrogen removal was revealed. It is clarified that with the CCS of 20 mm min−1 and an increase in the NP value from − 20 to − 80 kPa, the hydrogen content is reduced from 1.0 to 0.3 ppm. The coordinated action of NP and melt flow induced by CCS can minimize the hydrogen content. When the NP value is − 80 kPa and the CCS is 10 mm min−1, the hydrogen content is as low as 0.2 ppm, and the hydrogen removal rate is 85.7
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