Synthesis of Axially Chiral Biaryl-2-Carboxamides through Pd(II)-Catalyzed Atroposelective C−H Olefination

Boyang Jiang,Gang Zhou, Ao-Lian Jiang,Tao Zhou,Bing-Feng Shi

Organic Chemistry Frontiers（2024）

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摘要

Herein, we developed a Pd(II)-catalyzed amide-directed atroposelective C−H olefination to the synthesis of axially chiral biaryls with N,N-disubstituted amide groups. A broad range of axially chiral biaryls were obtained in...

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