Enhanced mechanical endurance and power conversion efficiency in flexible Cu2ZnSnS4 solar cells using ZnO/Ag-Ag2O/ZnO film

Cu2ZnSnS4 (CZTS) solar cells occupy an important direction in the field of clean energy research due to their environmental friendliness, low cost, and industrial technology compatibility. The complex and variable usage environment also accelerates the development of flexible CZTS solar cells. However, the inferior flexibility of ITO films limited their development. ZnO/Ag/ZnO (ZAZ) films are potential choices for transparent conductive layers of CZTS solar cells due to their high transmittance, conductivity, and flexibility. To further enhance the photovoltaic performance and mechanical durability of ZAZ films and solar cells, Ag2O was introduced into ZAZ film by magnetron sputtering. An ultra-high average transmittance of 96.6% in 400-800nm was achieved for ZnO/Ag-Ag2O/ZnO (ZAAZ) films at Ag2O sputtering power of 40W, which was attributed to the fact that Ag2O effectively inhibited the growth of 3D islands of Ag film, and formed a more uniform Ag film. ZAAZ films offered a superior figure of merit value of 0.1041 Ω-1. The power conversion efficiency (PCE) of ZAAZ solar cells was 6.94%, higher than that of ZAZ solar cells (6.69%). Remarkably, the PCE of ZAAZ solar cells was 7.9% higher than that of ZAZ solar cells after 1,000 bending cycles. Therefore, Therefore, this approach may provide a promising way to improve the photovoltaic performance and mechanical durability of flexible solar cells.