A europium shuttle for launching perovskites to space: using Eu²⁺/Eu³⁺ redox chemistry to boost photostability and radiation hardness of complex lead halides

Marina I. Ustinova,Lyubov A. Frolova, Alexandra V. Rasmetyeva,Nikita A. Emelianov, Maxim N. Sarychev,Gennadii V. Shilov,Pavel P. Kushch,Nadezhda N. Dremova,Galina A. Kichigina,Andrey I. Kukharenko, Dmitry P. Kiryukhin,Ernst Z. Kurmaev,Ivan S. Zhidkov,Pavel A. Troshin

Journal of Materials Chemistry A（2024）

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摘要

The incorporation of Eu2+ cations in lead-halide perovskites improves their photostability and radiation hardness with respect to γ-rays and high-energy electron fluences, which are the key prerequisites for aerospace applications of PSCs.

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A europium shuttle for launching perovskites to space: using Eu2+/Eu3+ redox chemistry to boost photostability and radiation hardness of complex lead halides

A europium shuttle for launching perovskites to space: using Eu²⁺/Eu³⁺ redox chemistry to boost photostability and radiation hardness of complex lead halides