Improvement of Plastic Deformation Property and Current Carrying Capacity of Bi2212 Wires through Low Oxygen Partial Pressure Post-Annealing of Precursor

The performance of superconducting magnets is greatly dependent on the size and uniformity of the superconducting filaments within the wire. However, in the fabrication of Bi2Sr2CaCu2Ox (Bi2212) wires using ceramic oxide as the superconducting filaments, we face multiple challenges including filament fragility, poor uniformity, and non-smooth Ag/superconductor interfaces. These challenges primarily stem from the significantly lower plastic deformation capability of ceramic oxide powder filaments compared to metal matrices. To address these challenges, this study focuses on the modification of ceramic oxide precursor powders. Through the utilization of low-temperature, low oxygen partial pressure (pO2) heat treatment, we have observed significant changes in the Cu chemical states and lattice parameters within the Bi2212 grains. These alterations have proven to be highly effective in reducing the energy required for grain sliding and, in turn, enhancing the plastic deformation properties of the Bi2212 oxide filament. Furthermore, post-annealing the oxide powder under low pO2 conditions narrows the gap in plastic deformability between the Ag sheath and the oxide filaments, resulting in improved filament uniformity and a smoother Ag/oxide interface in Bi2212 wires. Notably, the Bi2212 grains exhibit an orderly arrangement within the wires. As a result of these improvements, the critical current density (Jc) of the final wires increases by an impressive 70%. The outcomes of this study are not only crucial for producing Bi2212 magnets with higher magnetic field strength, improved magnetic field uniformity, and enhanced operational stability, but also offer fresh insights and methodologies for advancing the field of superconducting materials.