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Cage-Rearranged and Cage-Intact Syntheses of Azido-Functionalized Larger T10 and T12 POSS

Hui Wang, Ming-Xi Nie,Xiong Lin,Xiangqian Li, Hao Liu,Qing-Yun Guo,Di Han, Qiang Fu

Dalton Transactions（2024）

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Abstract
Herein we investigate the product type and distribution during the synthesis of azido-functionalized larger polyhedral oligomeric silsequioxanes (POSSs) using 3-chloropropyl- and chloromethyldimethylsilylethyl-functionalized T8, T10, and T12 POSSs as precursors. Our...
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