A novel ratiometric fluorescent sensor based on terpyridine derivatives for Zn2+ in aqueous solution
AUSTRALIAN JOURNAL OF CHEMISTRY(2024)
摘要
Terpyridine and its derivatives have good binding affinity for most transition metal ions due to the arrangement of their three pyridine nitrogen atoms. In this work, a new ratiometric fluorescent probe G , which is based on a styrylpyridinium attached to a terpyridine fluorophore, was synthesized and characterized. The fluorescence spectrum of probe G shows a good response to Zn2+ by an intramolecular charge transfer effect. On increasing the concentration of Zn2+, the fluorescence color of probe G changes from blue to yellow. Importantly, probe G has a high selectivity for Zn(2+)and is not affected by other metal ions, including Cd2+. In addition, the limit of detection (LOD) of probe G for Zn2+ was found to be up to 0.17 mu M. The results show that probe G has the ability to selectively recognize Zn2+ in aqueous solution.
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关键词
aqueous solution,anti-interference,fluorescent chemosensor,high selectivity,low detection limit,ratiometric fluorescent,terpyridine,Zn2+
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