The 9-Vinyl-9H-carbazole-3,6-dicarbonitrile

Kristina Svetlova, Alexander Kazantsev,Oleg Levin, Sofia Filippova,Elena Alekseeva

MOLBANK(2024)

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摘要
Carbazole polymers attract significant attention as promising luminophores, organic electronic and photovoltaic materials, photo/electrocatalysts, energy storage materials, redox mediators and catalysts. However, the oxidation potential of the commercially available poly(vinylcarbazole) is insufficient for some applications such as high-voltage Li-Ion batteries. We have proposed a monomer for the novel polycarbazole with an increased oxidation potential, which will be compatible with high-voltage cathode materials for Li-Ion. In addition, the proposed polymer is an interesting substrate for the further carbonization to obtain N-doped carbons with a high electrocatalytic activity level.
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关键词
carbazole,vinylation,one pot,cyanation
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