Two-Step High-Temperature Calcination of BiVO4/TiO2/Ti3C2 Nanocomposites as a High-Efficiency Photoelectrochemical Platform for Enhanced Photovoltaic Performance

ACS APPLIED NANO MATERIALS(2024)

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Abstract
Environmental issues, such as increasingly polluted water resources and energy shortages, have led to the need for new strategies to promote sustainable progress and enhance human well-being. Photocatalysis is widely recognized as a promising technology for environmental sustainability. MXene is a two-dimensional nanotransition metal material, which has attracted extensive attention in the field of photocatalysis. In MXenes, titanium carbide (Ti3C2) has been extensively studied for its application in photocatalysis due to its unique nanolayered structure. The Ti site on the surface of Ti3C2 has a stronger redox activity than traditional C materials, and Ti3C2 has high electrical conductivity. The focus of this study is to obtain the Ti3C2/TiO2 composite by in situ calcination of Ti3C2 and then combine Mo,W:BVO with TiO2 to form feasible heterojunctions. The excellent electrical conductivity of Ti3C2 promotes the transfer of electrons and holes between Mo,W:BVO and TiO2, thus establishing a cascade that minimizes charge carrier recombination and exhibits strong photocatalytic activity. Through a series of photocatalytic tests, the optimum calcination temperature and time of Ti3C2 (550 degrees C, 2.5 h) and the doping amount of Ti3C2 (2 mg/mL) were determined. Under these conditions, a high current density of 3.8 mA cm(-2) was obtained, showing excellent photostability. This study confirmed the strong photocatalytic activity of the synthesized nanoscale composites Mo,W:BVO/TiO2/Ti3C2, providing valuable insights for the design of efficient and sustainable photocatalysts in the future.
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Key words
Mo,W:BVO,titanium dioxide (Ti3C2),Z-scheme,photocatalysis,heterojunction
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