The effect of ligand/ metal-ligand ratio on the structural architectures of five different 1D zinc(II) coordination polymers with pyridyl derivative ligands

Five coordination compounds, [Zn(bppc)Cl]n & sdot;0.5nH2O (1) [Zn2(bppc)2(suc)]n (2), [Zn(dppb)Cl]n & sdot;nH2O (3) [Zn (dppb)Cl]n (4) [Zn2(dppb)2(bdc)]n & sdot;2nH2O(5) (Hbppc =2,6-bis(pyrazin-2-yl)pyridine-4-carboxylic acid, H2suc=succinic acid, Hdppb=4-(2,6-di(pyrazin-2-yl)pyridine-4-yl)-benzoic acid, H2bdc=1,4-benzenedicarbox- ylic acid), with the same one dimensions but different patterns have been hydrothermally synthesized and structurally characterized. Single crystal X-ray analysis revealed that compound 1 shows one-dimensional wave chain structure, compound 2 to 5 show one-dimensional ladder chain structure, one-dimensional V-shaped chain structure, one-dimensional linear chain structure and one-dimensional A-shaped chain structure, respectively. The structure differences of 1-5 show that ligand including auxiliary ligand and metal-ligand ratio have important influence on the final structures. Additionally, the luminescent properties of 1-5 have been investigated with fluorescent spectra in the solid state and fluorescence sensing experiments show that compound 1 exhibit a great selectivity and sensitivity for detection of Cu2+ion and nitrobenzene.