Coordination-driven Assembly of Dysprosium Layers into Framework Featuring Enhanced Energy Barrier and Quantum Tunneling of Magnetization
Inorganic Chemistry Frontiers(2024)
摘要
An orchestrated reaction of Dy(ClO4)3.6H2O with the organic ligand of Nʹ-(2-hydroxybenzylidene)pyrazine-N-oxide-carbohydrazide (H2L) affords a layered building block, denoted as {[Dy(L)(H2O)(CH3OH)]ClO4·2CH3OH}n (1). Subsequently, the coordinated water and methanol molecules in 1...
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