Coordination-driven Assembly of Dysprosium Layers into Framework Featuring Enhanced Energy Barrier and Quantum Tunneling of Magnetization

Inorganic Chemistry Frontiers(2024)

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摘要
An orchestrated reaction of Dy(ClO4)3.6H2O with the organic ligand of Nʹ-(2-hydroxybenzylidene)pyrazine-N-oxide-carbohydrazide (H2L) affords a layered building block, denoted as {[Dy(L)(H2O)(CH3OH)]ClO4·2CH3OH}n (1). Subsequently, the coordinated water and methanol molecules in 1...
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