Appropriation of group II metals: synthesis and characterisation of the first alkaline earth metal supported transition metal carbonite complexes

Nickel carbonite complexes supported by alkaline earth metals have been accessed via salt-metathesis of the corresponding alkali metal precursors. The new complexes undergo Schlenk-like exchange reactions in solution which have been investigated by NMR spectroscopy. Also their reactivity towards epoxides and carbon monoxide was studied. Complexes where magnesium and calcium ions assist CO2 activation at nickel centres have been accessed and were found to enter into Schlenk-type equilibria.