Effects of modified coal gasification fine slag on the processing and mechanical properties of natural rubber composites

Coal gasification fine slag (CGFS) is rich in unburned residual carbon, silica and alumina, and has a large specific surface area, making it a potential polymer-reinforcing filler. Tea polyphenol (TP)-modified coal gasification fine slag (TP-CGFS-T) was prepared using flotation and modification methods in this study. The effects of unmodified and modified CGFS-T on the sulfurization performance, processing properties, thermal stability, fracture morphology, and mechanical properties of natural rubber composite materials were investigated. Results indicated that after TP modification, CGFS-T exhibited highly uniform dispersion on the surface without the agglomeration of fillers. When the dosage of TP-CGFS-T was 20 phr, the comprehensive performance of the natural rubber (NR) composite material was optimal, with a tensile strength of 12.12 MPa, the elongation at break of 1208.83%, the tear strength of 30.94 kN/m, and the shore hardness of 38.7 A. As the amount of TP-CGFS-T increased, the scorch time of NR increased, which enhanced the processing safety of rubber. This study provides a strategy for treating CGFS, which can both reduce the pollution caused by CGFS and save costs for NR composite materials.Highlight The CGFS is separated into concentrate and tailings by flotation. The compatibility between fillers and the matrix is enhanced by TP modification of CGFS-T. The composite materials show excellent mechanical and processing properties. Coal gasification fine slag separation and modification process diagram. image