The Effect of Rare Earth Y on the Inhibitor Precipitation Behavior of Strip‐Cast Grain‐Oriented Silicon Steel

steel research international(2024)

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摘要
0.3 mm‐thick grain‐oriented silicon steel sheets with varying Y contents are produced via twin‐roll strip‐casting and two‐stage cold rolling process. This study primarily investigates the evolution of microstructure, texture, and precipitation along the processing. Specifically, the effect of rare earth Y on second‐phase particle precipitation in ultralow carbon grain‐oriented silicon steel is examined. Results indicate that higher Y content will consume beneficial inhibitor elements such as S and N, leading to the formation of coarse rare earth inclusions (≈10 μm) in the cast strip. This significantly diminishes inhibition ability and magnetic induction (B8 = 1.58 T≈1.71 T). On the contrary, the addition of trace Y can accelerate the precipitation of inhibitors. During the intermediate annealing stage, steel with trace Y exhibits a significant enhancement in precipitate distribution density (from 2.8 μm−2 to 13.6 μm−2), and the final magnetic induction B8 increases from 1.86 T to 1.91 T compared to steel without Y. In addition, the results of first‐principle calculations based on density functional theory reveal that the doped Y atom prefers to segregate at the Al–N interface, and the interface energy reduces from 1.871 J m−2 to 1.024 J m−2, thereby promoting the precipitation of AlN.
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