Substrate-Dependent Mechanism Switch in the Desaturation Reactions of the Mononuclear Nonheme Iron Enzyme PtlD

Linyue Chen,Qian Deng, Tingting Ma,Jiayue Gu, Juan Yang,Xuan Zhang,You-Quan Zou,Zixin Deng, Li Chen,Changming Zhao

ACS Catalysis（2024）

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关键词

alpha-ketoglutarate-dependent mononuclear nonheme iron dioxygenase,desaturation reaction,solvent isotope effect,kinetic isotope effect,carbocation intermediate,hydrogen tunneling

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