Bimetallic Nitride TiVN Hollow Nanotubes for High-Performance Zinc-Ion Hybrid Supercapacitors

Zinc-ion hybrid supercapacitors (ZIHCs) hold great promise in the realm of renewable energy storage. However, their development is severely hampered by the unsatisfactory practical capacity and poor stability. Herein, we report an effective strategy to improve the electrochemical performance by constructing hollow bimetallic nitride TiVN (H-TiVN) using a sacrificial template method. The optimized H-TiVN//Zn shows a high capacitance of 183.7 F g(-1) at 0.2 A g(-1) along with excellent stability (an 84.7% capacitance retention after 20,000 cycles at 5 A g(-1)). More importantly, the energy density can reach 57.42 Wh kg(-1), accompanied by a power density of 249.35 W kg(-1). Our work not only establishes H-TiVN as a high-performance electrode material for ZIHCs but also provides a general strategy for improving the electrochemical performance of nanomaterial electrodes.