Carbon quantum dots/carbon-coated SnS2 as a high-performance potassium-ion battery cathode material

Ionics(2024)

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摘要
Potassium-ion batteries (PIBs) are considered to be an alternative to lithium-ion batteries because of their more affordable manufacturing cost and lower potential (2.936 V compared to standard hydrogen electrodes). However, the large ionic radius and unstable structure of potassium ions have hindered their satisfactory electrochemical performance from being satisfactory. In this study, a layered SnS2@CQDs composite material was prepared using hydrothermal and pyrolysis methods as a promising anode material for PIBs. The composite material possessed a significant specific surface area, and the layered structure of SnS2 contributed to its unique potassium-ion intercalation/deintercalation properties. The anchoring of the CQDs and carbon coating restricted the volume effect of SnS2 and enhanced the electron transfer efficiency. PIBs prepared from this electrode exhibited a high potassium storage capacity (235 mA h g−1 after 120 cycles at 100 mA g−1) and excellent cycling stability (144.8 mA h g−1 after 500 cycles at 500 mA g−1).
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关键词
SnS2,Carbon quantum dots,Nanosheets,Anode,Potassium-ion batteries
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