A strong hydrogen bond bridging interface based on tannic acid for improving the performance of high-filled bamboo fibers/poly (butylene succinate-co-butylene adipate) (PBSA)biocomposites.

Natural plant fiber-reinforced bio-based polymer composites are widely attracting attention because of their economical, readily available, low carbon, and biodegradable, and showing promise in gradually replacing petroleum-based composites. Nevertheless, the fragile interfacial bonding between fiber and substrate hinders the progression of low-cost and abundant sustainable high-performance biocomposites. In this paper, a novel high-performance sustainable biocomposite was built by introducing a high density strong hydrogen-bonded bridging interface based on tannic acid (TA) between bamboo fibers (BFs) and PBSA. Through comprehensive analysis, this strategy endowed the biocomposites with better mechanical properties, thermal stability, dynamic thermo-mechanical properties and water resistance. The optimum performance of the composites was achieved when the TA concentration was 2 g/L. Tensile strength as well as modulus, flexural strength as well as modulus, and impact strength improved by 22 %, 10 %, 15 %, 35 %, and 25 % respectively. Additionally, the initial degradation temperature(Tonset) and maximum degradation temperature(Tmax) increased by 12.07 °C and 14.8 °C respectively. The maximum storage modulus(E'), room temperature E', and loss modulus(E")elevated by 199 %, 75 %, and 181 % respectively. Moreover, the water absorption rate decreased by 59 %. The strong hydrogen-bonded bridging interface serves as a novel model and theory for biocomposite interface engineering. At the same time, it offers a promising future for the development of high performance sustainable biocomposites with low cost and abundant biomass resources and contributes to their wide application in aerospace, automotive, biomedical and other field.