Two-stage growth for highly ordered epitaxial C_60 films on Au(111)
arxiv(2024)
摘要
As an organic semiconductor and a prototypical acceptor molecule in organic
photovoltaics, C_60 has broad relevance to the world of organic thin film
electronics. Although highly uniform C_60 thin films are necessary to
conduct spectroscopic analysis of the electronic structure of these
C_60-based materials, reported C_60 films show a relatively low degree
of order beyond a monolayer. Here, we develop a generalizable two-stage growth
technique that consistently produces single-domain C_60 films of
controllable thicknesses, using Au(111) as an epitaxially well-matched
substrate. We characterize the films using low-energy electron diffraction,
low-energy electron microscopy, scanning tunneling microscopy, and
angle-resolved photoemission spectroscopy (ARPES). We report highly oriented
epitaxial film growth of C_60/Au(111) from 1 monolayer (ML) up to 20 ML
films. The high-quality of the C_60 thin films enables the direct
observation of the electronic dispersion of the HOMO and HOMO-1 bands via ARPES
without need for small spot sizes. Our results indicate a path for the growth
of organic films on metallic substrates with long-range ordering.
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