A heat-resistant explosive featuring an N,N′-ethylene bridged 1,2,4-1H-triazole fused ring
New Journal of Chemistry(2024)
摘要
Six energetic compounds bridged by N,N '-alkyl groups were synthesized in a straightforward manner in 1-3 steps from 3-nitro-1H-1,2,4-triazol-5-amine (ANTA). Among these compounds, 2,7-dinitro-10,11-dihydrobis([1,2,4]triazolo)[5,1-c:1 ',5 '-g][1,2,4,7]tetrazocine (2) exhibits a decomposition temperature exceeding 300 degrees C (T-d(onset) = 319 degrees C), with superior density and detonation performance (rho = 1.83 g cm(-3), D-v = 8157 m s(-1)) to HNS. N,N '-(Methylenebis(3-nitro-1H-1,2,4-triazole-1,5-diyl))dinitramide (5) has the highest density (rho = 1.91 g cm(-3)) with the best comprehensive detonation performance (D-v = 9079 m s(-1), P = 36.1 GPa), and is comparable to HMX. Insight into the relationship between stability and structure revealed that 1,2,4-triazole-based compounds with an N,N '-ethylene bridge consistently exhibit superior stability compared to those with an N,N '-methylene bridge. This provides a new way to design fused ring explosives with high stability.
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