Unlocking Anti-Aging Potential: Flame Retardants Thrive Without Added Antioxidants

A synergistic flame retardant with a core-shell structure utilizes the 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) derivative as the outer shell and ammonium polyphosphate (APP) as the inner core. Three derivatives of DOPO (DOPO-GY, DOPO-DH and DOPO-GD) are synthesized by reacting DOPO with glyoxal, paraformaldehyde and diethanolamine, and glutaraldehyde, respectively. DOPO-GY@APP, DOPO-DH@APP and DOPO-GD@APP exhibit good radical scavenging activities. The oxidation induction time for EVA/DOPO-GY@APP is exceptionally high at 19.04 minutes, in contrast to EVA alone, which has an induction time of only 5.51 minutes. Simultaneously, after aging at 180 °C and 165 °C for 7 days, the retention rates of elongation at break for EVA/DOPO-GY@APP are 34.67% and 55.50%, respectively. These findings demonstrate the long-term anti-aging properties of EVA/DOPO-GY@APP without the need for additional antioxidants. Moreover, EVA/DOPO-GY@APP, EVA/DOPO-DH@APP and EVA/DOPO-GD@APP all achieve V-0 rating with 25% addition of flame retardant. In comparison to pure EVA, their peak heat release rates and maximum smoke density decrease by 52% and 47%, 43% and 54%, and 51% and 44%, respectively. Additionally, compared to EVA/APP, their mechanical properties have been improved. Therefore, these microencapsulated flame retardants with DOPO derivatives as the shell effectively enhance the mechanical properties and fire safety of EVA composites.