Solvent-free synthesis and chiroptical properties of a C–N axially chiral cruciform dimer of benzo[b]phenoxazine

Shuhei Ishikawa,Daisuke Sakamaki,Masayuki Gon,Kazuo Tanaka,Hideki Fujiwara

Chemical Communications（2024）

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摘要

A novel C–N axially chiral molecule composed of two tert-butyl-substituted benzo[b]phenoxazine (BPO) was synthesized via solvent-free reactions. The absolute configurations of the enantiomers were determined by X-ray single-crystal analysis. The...

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