From field-induced to zero-field SMMs associated with open/closed structures of bis(ZnDy) tetranuclear complexes: a combined magnetic, theoretical and optical study

Andoni Zabala-Lekuona,Xabier Lopez de Pariza,Ismael Francisco Díaz-Ortega,Javier Cepeda,Hiroyuki Nojiri,Nina P. Gritsan,A. A. Dmitriev,Alberto López-Ortega,Antonio Rodríguez Diéguez,José Manuel Seco,Enrique Colacio

Dalton Transactions（2024）

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Abstract

We have prepared a bis(compartmental) Mannich base ligand H4L (1,4,8,11-tetraaza-1,4,8,11-tetrakis(2-hydroxy-3-methoxy-5-methylbenzyl)cyclotetradecane) specifically designed to obtain bis(TMIILnIII) tetranuclear complexes (TM = transition metal). In this regard, we have succeeded in obtaining three...

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