Toward Circular Recycling of Polyurethanes: Depolymerization and Recovery of Isocyanates
JACS AU(2024)
摘要
We report a depolymerization strategy to nearly quantitatively regenerate isocyanates from thermoplastic and thermoset polyurethanes (PUs) and then resynthesize PUs using the recovered isocyanates. To date, chemical/advanced recycling of PUs has focused primarily on the recovery of polyols and diamines under comparatively harsh conditions (e.g., high pressure and temperature), and the recovery of isocyanates has been difficult. Our approach leverages an organoboron Lewis acid to depolymerize PUs directly to isocyanates under mild conditions (e.g., similar to 80 degrees C in toluene) without the need for phosgene or other harsh reagents, and we show that both laboratory-synthesized and commercially sourced PUs can be depolymerized. Furthermore, we demonstrate the utility of the recovered isocyanate in the production of second-generation PUs with thermal properties and molecular weights similar to those of the virgin PUs. Overall, this route uniquely provides an opportunity for circularity in PU materials and can add significant value to end-of-life PU products.
更多查看译文
关键词
Polyurethane,depolymerization,isocyanate,chemical recycling,closed-loop,life-cyclemanagement
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要