Noncontact Microfluidics of Highly Viscous Liquids for Accurate Self-Splitting and Pipetting

Xiao Han,Shengda Tan, Qi Wang, Xiaobiao Zuo,Liping Heng,Lei Jiang

ADVANCED MATERIALS(2024)

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摘要
Accurate dosing for various liquids, especially for highly viscous liquids, is fundamental in wide-ranging from molecular crosslinking to material processing. Despite droppers or pipettes being widely used as pipetting devices, they are powerless for quantificationally splitting and dosing highly viscous liquids (>100 mPa s) like polymer liquids due to the intertwined macromolecular chains and strong cohesion energy. Here, a highly transparent photopyroelectric slippery (PS) platform is provided to achieve noncontact self-splitting for liquids with viscosity as high as 15 000 mPa s, just with the assistance of sunlight and a cooling source to provide a local temperature difference (Delta T). Moreover, to guarantee the accuracy for pipetting liquids (>80%), the ultrathin MXene film (within a thickness of 20 nm) is self-assembled as the photo-thermal layers, overcoming the trade-off between transparency and photothermal property. Compared with traditional pipetting strategies (approximate to 1.3% accuracy for pipetting polymer liquids), this accurate microfluidic chip shows great potential in adhesive systems (bonding strength, twice than using the droppers or pipettes).
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关键词
accurate self-splitting,highly viscous liquids,monolayer self-assembly,noncontact microfluidics,slippery surface
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